Acoustical studies on ion-solvent interaction of some electrolytes in aqueous DMF mixed solvent system at different temperatures

Author & Affiliation:
R. PALANI (palani_physics06@yahoo.co.in
Department of Physics, D.D.E., Annamalai University, Annamalainagar-608-002 (INDIA)
A. Geetha
Department of Physics, D.D.E., Annamalai University, Annamalainagar-608-002 (INDIA)
S. Balakrishnan
Department of Physics, D.D.E., Annamalai University, Annamalainagar-608-002 (INDIA)
M. Catherine
Department of Physics, D.D.E., Annamalai University, Annamalainagar-608-002 (INDIA)
Keyword:
Ultrasonic velocity, apparent molar volume, hydration number
Issue Date:
December 2008
Abstract:

Density (r), viscosity (h) and ultrasonic velocity (U) have been measured for sodium halide solutions namely sodium fluoride (NaF), sodium chloride(NaCl), sodium bromide (NaBr) in aqueous dimethylformamide (DMF) (1m) at 303, 308 and 313K. Using the experimental values, the adiabatic compressibility (β), hydration number (nH), apparent molal compressibility (φk), apparent molal volume (φv), limiting apparent molal compressibility (φok), limiting apparent molal volume(φov) and their constants (SK, SV) and viscosity A and B coefficients of Jones-Dole equation were calculated and the results have been discussed in terms of ion-solvent interactions.
 

Pages:
485-492
ISSN:
2319-8052 (Online) - 2231-3478 (Print)
Source:
DOI:
jusps-B
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Copy the following to cite this article:

R. Palani; A. Geetha; S. B. ; M. Catherine, "Acoustical studies on ion-solvent interaction of some electrolytes in aqueous DMF mixed solvent system at different temperatures ", Journal of Ultra Scientist of Physical Sciences, Volume 20, Issue 3, Page Number 485-492, 2018

Copy the following to cite this URL:

R. Palani; A. Geetha; S. B. ; M. Catherine, "Acoustical studies on ion-solvent interaction of some electrolytes in aqueous DMF mixed solvent system at different temperatures ", Journal of Ultra Scientist of Physical Sciences, Volume 20, Issue 3, Page Number 485-492, 2018

Available from: http://www.ultraphysicalsciences.org/paper/1329/

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